So, If you are facing similar issue then follow this ....
Open VLC preference settings: Go to Settings --> Preferences
From the preference window go to Video --> Output modules and select the "Advance option" and select the video output module as "X11 Video Output" from the drop down
Save the settings and restart VLC and now you should able to see the video under compiz.
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source:http://linuxpoison.blogspot.com/2008/09/13578175719566.html